Kinnu

What Is The Periodic Table?

Introduction to the Periodic Table

Chemical elements are the building blocks that make up everything you see, hear, smell and touch. They are substances that cannot be broken down further using ordinary chemical reactions. Each element is distinguished by its atomic structure, specifically the number of protons it has in its nucleus. These elements combine in various ways to form the diverse array of substances we encounter in our daily lives.

Sandbh, CC BY-SA 4.0 <https://creativecommons.org/licenses/by-sa/4.0>, via Wikimedia Commons.

The modern periodic table is a systematic way to organize these elements. It arranges them by atomic number, which is the number of protons in an element's nucleus. This arrangement results in groups of elements that share similar properties. This is because the properties of an element are largely determined by the structure of its atoms, particularly the arrangement of its electrons.

Currently, there are 118 known elements. Each of these elements has its own unique story, from its discovery to its uses in modern society. In this pathway, we will focus on the stories of nine specific elements, which, between them, demonstrate several of the key properties that elements can possess.

The classification of elements has been a subject of scientific inquiry since the late 18th century. Antoine Lavoisier, a French chemist, made one of the earliest attempts to classify elements. In 1789, he divided them into metals and nonmetals, a basic distinction that is still recognized today.

Dmitri Mendeleev, creator of the periodic table. Image: https://pixel17.com via Wikimedia.

The modern periodic table, however, owes its structure to Dmitri Mendeleev. In 1869, Mendeleev arranged the known elements by atomic weight, and he left gaps for elements that were yet to be discovered. This was a revolutionary idea at the time, and it allowed for the prediction of the properties of these undiscovered elements.

Mendeleev's periodic table has proven to be remarkably accurate. It has correctly predicted the existence and properties of several elements, including gallium, scandium, and germanium. Today, the periodic table is organized by atomic number rather than atomic weight, but the basic framework that Mendeleev established remains intact.

Atoms are the smallest units of an element. They are the fundamental units of matter as we know it, and they are composed of even smaller particles: protons, neutrons, and electrons. Different combinations of these subatomic particles are what makes one element different to another.

The structure of an atom. Image: AG Caesar, CC BY-SA 4.0 <https://creativecommons.org/licenses/by-sa/4.0>, via Wikimedia Commons

The atomic nucleus is the core of an atom. It is positively charged and is surrounded by a cloud of negatively charged electrons. The nucleus contains protons, which contribute to the positive charge, and neutrons, which are neutral. The number of protons in the nucleus determines the atomic number of an element, which is the defining characteristic of each element.

The atomic nucleus was discovered by Ernest Rutherford through his gold foil experiment, shooting positively charged alpha particles at a piece of gold foil. He found that most of the atom's mass is concentrated in the nucleus, which is composed of protons and neutrons. The electrons, while essential for chemical reactions, contribute very little to the atom's overall mass due to their extremely small size.

The atomic mass of an element is the average mass of its atoms. It is measured in atomic mass units (amu), also known as daltons (D). The atomic mass takes into account the mass of both the protons and neutrons in the nucleus, as these particles make up the majority of an atom's mass. To calculate the atomic mass, you simply add the number of protons and neutrons together.

The atomic mass is an important property of an element. It is used in calculations in chemistry, such as determining the amount of an element in a sample or predicting the outcome of a chemical reaction. The atomic mass is also used to calculate the molar mass of compounds, which is essential for stoichiometry. Stoichiometry is the study of the amount of a substance required in chemical reactions — both in terms of initial reactants and the resultant products.

A diagram showing the Stoichiometry of the Combustion of Methane. Notice, the amount of each type of element stays the same. Image: JyntoRobert A. RohdeJacek FHJynto, Public domain, via Wikimedia Commons

The atomic number, on the other hand, is the number of protons in an atom's nucleus. It is the defining characteristic of an element. For example, an atom with six protons is always a carbon atom. The atomic number is used to organize the elements in the periodic table.

Sandbh, CC BY-SA 4.0 <https://creativecommons.org/licenses/by-sa/4.0>, via Wikimedia Commons.

Mendeleev’s original periodic table arranged elements by relative atomic mass. The modern periodic table, on the other hand, arranges them by atomic number, which is the number of protons in an atom's nucleus.

The periodic table is divided into horizontal rows called periods and vertical columns called groups. Elements in the same period have the same number of electron shells, while elements in the same group have the same number of electrons in their outermost shell, known as valence electrons. This arrangement results in groups of elements that share similar properties.

The arrangement of the periodic table reflects the periodic law proposed by Mendeleev. This law describes the fact that certain properties periodically reoccur across elements in the table. For example, the alkali metals in Group 1 such as lithium and potassium have quite major differences in their atomic numbers, but also share similar material properties.

In the case of Group 1 metals, this is that they are all highly reactive. They are also good conductors of heat and electricity: all because of their similar atomic structures.

Atomic Structure and Isotopes

Isotopes are different forms of the same element that have the same number of protons but different numbers of neutrons. This means that while they have the same atomic number, they have different atomic masses. Even though isotopes of an element have different numbers of neutrons, they still exhibit the same chemical behavior because they have the same number of protons and electrons. This is why they are considered the same element.

Carbon-12 and carbon-14 are examples of isotopes. Both have 6 protons, but carbon-12 has 6 neutrons while carbon-14 has 8. The ratio of these isotopes in a sample can be used in carbon dating, a method used to determine the age of organic remains up to 60,000 years old.

The chemical properties of an element are determined by the arrangement of its electrons, particularly the electrons in its outermost shell, known as valence electrons. These properties include chemical reactivity, flammability, and reactivity with acids. Electrons are arranged in shells around the nucleus. The further a shell is from the nucleus, the larger it is and the more electrons it can hold.

The electrons in the outermost shell have the highest energy and are the most involved in chemical reactions. The number and arrangement of valence electrons determine an element's chemical properties. These electrons are involved in forming chemical bonds with other atoms. For example, sodium and chlorine atoms bond to form table salt, with sodium donating an electron to chlorine to become sodium chloride.

The physical properties of an element, such as color, density, melting point, and boiling point, are key to its identification and classification. These properties can be observed or measured without changing the composition of the material. Physical properties are determined by the structure of an element's atoms and the way they interact with each other. For example, the density of an element is determined by the mass of its atoms and the space they occupy.

The various cool properties of different elements. Image: Bionerd, Ivar Leidus, Alchemist-hp and Jurii via Wikimedia

Metals, which make up about 80% of the elements on the periodic table, have distinctive physical properties. They tend to have a shiny luster, conduct heat and electricity, have high tensile strength, and are solid at room temperature, with the exception of mercury. These properties are a result of the structure of metal atoms and the way their electrons are arranged.

Periodic trends are patterns in the properties of elements that occur across periods and groups on the periodic table. These trends help predict the chemical behavior of elements and are a result of the periodic law proposed by Mendeleev.

An illustration of periodic trends on the periodic table. Sandbh, vector + translation by Habitator terrae, CC BY-SA 4.0 <https://creativecommons.org/licenses/by-sa/4.0>, via Wikimedia Commons

Major periodic trends include electronegativity, ionization energy, atomic radius, and electron affinity. Electronegativity is a measure of an atom's ability to attract electrons in a chemical bond. Ionization energy is the energy required to remove an electron from an atom. Atomic radius is the size of an atom. Electron affinity is the energy change that occurs when an electron is added to a neutral atom.

These trends can be explained by the structure of atoms. For example, atomic radius decreases as you move from left to right across a period. This is because the number of protons in the nucleus increases, pulling the electrons in closer and reducing the size of the atom.

On the other hand, atomic radius increases as you move down a group because additional electron shells are added, increasing the size of the atom.